Zhao, Zhen-Guo and Yu, Rong-Min and Wu, Xiao-Yuan and Zhang, Qi-Sheng and Xie, Yi-Ming and Wang, Fei and Ng, Seik Weng and Lu, Can-Zhong (2009) One-pot synthesis of two new copper(i) coordination polymers: in situ formation of different ligands from 4-aminotriazole. CrystEngComm, 11 (11). pp. 2494-2499. ISSN 1466-8033, DOI https://doi.org/10.1039/b821491c.
Full text not available from this repository.Abstract
Two Cu4I4 coordination polymers, [Cu 2I2(aadtz)]n (1) and [Cu2I(dtz)] n (2) [aadtz = 4-[(1-aminoethylidene)-amino]-3,5-diethyl-1,2,4- triazole, dtz = 3,5-diethyl-1,2,4-triazole], were synthesized in a one-pot reaction of CuI and 4-amino-3,5-diethyl-1,2,4-triazole under solvothermal conditions. The organic components were generated in situ from a common triazolate source. The structures of the Cu4I4 units in the polymers are different. The Cu4I4 cluster in complex 1 is an inorganic 8-membered ring with a chair-chair conformation, while the one in complex 2 is a distorted cubane. The topologies of the complexes were assigned as a two-dimensional 4-connected grid for 1 and a three-dimensional (3,4)-connected jph-type framework for 2. In addition, the luminescent properties of the complexes in the solid state were also investigated. © 2009 The Royal Society of Chemistry.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Cuprous Iodide; Xantpho; Phosphine |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 13 Jul 2020 08:24 |
| Last Modified: | 13 Jul 2020 08:24 |
| URI: | http://eprints.um.edu.my/id/eprint/25093 |
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