Kinetic and thermodynamic analysis of iron oxide reduction by graphite for CO 2 mitigation in chemical‐looping combustion

Ubando, Aristotle T. and Chen, Wei Hsin and Show, Pau Loke and Ong, Hwai Chyuan (2020) Kinetic and thermodynamic analysis of iron oxide reduction by graphite for CO 2 mitigation in chemical‐looping combustion. International Journal of Energy Research, 44 (5). pp. 3865-3882. ISSN 0363-907X

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Official URL: https://doi.org/10.1002/er.5184

Abstract

Chemical-looping combustion (CLC) provides a platform to generate energy streams while mitigating CO2 using iron oxide as a carrier of oxygen. Through the reduction process, iron oxide experiences phase transformation to ultimately produce metallic iron. To understand iron oxide reduction characteristics and optimally design the fuel reactor, kinetic and thermodynamic analyses were proposed, utilizing graphite. This study aims to evaluate the reduction behavior under the non-isothermal process of various mixture ratios of hematite and graphite via thermogravimetric analysis with simultaneously evaluating evolved gases using a Fourier transform infrared spectrometer. The Coats-Redfern model was employed to approximate the kinetic and thermodynamic parameters which assessed the different reaction mechanisms together with the distributed activation energy model (DAEM). The results revealed that the hematite-to-graphite ratio of 4:1 had the highest reduction degree and had three distinct peaks representing three iron oxide reduction phases. The zero-order reaction mechanism agreed with the experimental results compared with other reaction models. The thermodynamic analysis showed an overall endothermic spontaneous reaction for the three phases which signified the direct reduction of the iron oxides. The DAEM result validated a stepwise reduction of iron oxides to metallic iron. The study aids the optimal design of the CLC fuel reactor for enhanced system performance. © 2020 John Wiley & Sons Ltd

Item Type: Article
Uncontrolled Keywords: chemical-looping combustion; Coats-Redfern model; distributed activation energy model; iron oxide and graphite; kinetics and thermodynamics; TGA
Subjects: T Technology > TJ Mechanical engineering and machinery
Divisions: Faculty of Engineering
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 11 Jun 2020 03:46
Last Modified: 11 Jun 2020 03:46
URI: http://eprints.um.edu.my/id/eprint/24794

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