Hydrostannolysis reactions-II. Reaction of phenolic esters with tri-n-butyltin hydride

Khoo, L.E. and Lee, H.H. (1970) Hydrostannolysis reactions-II. Reaction of phenolic esters with tri-n-butyltin hydride. Tetrahedron, 26 (18). pp. 4261-4268. ISSN 0040-4020

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Official URL: https://doi.org/10.1016/S0040-4020(01)93069-8

Abstract

Reaction of phenyl benzoate with tri-n-butyltin hydride has been found to give mainly toluene, benzyl benzoate, tri-n-butyltin phenoxide and tri-n-butyltin benzoate. Possible reaction paths leading to these products are discussed. A SH2 mechanism involving initial attack of tri-n-butyltin radical at the ethereal oxygen atom of the ester with displacement of the benzoyl moiety appears to be consistent with observed experimental evidence. © 1970.

Item Type: Article
Uncontrolled Keywords: Hydrostannolysis; phenolic; esters; tri-n-butyltin hydride
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Mr Jasny Razali
Date Deposited: 12 Mar 2021 01:31
Last Modified: 12 Mar 2021 01:31
URI: http://eprints.um.edu.my/id/eprint/24613

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