Khoo, L.E. and Lee, H.H. (1970) Hydrostannolysis reactions-II. Reaction of phenolic esters with tri-n-butyltin hydride. Tetrahedron, 26 (18). pp. 4261-4268. ISSN 0040-4020, DOI https://doi.org/10.1016/S0040-4020(01)93069-8.
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Official URL: https://doi.org/10.1016/S0040-4020(01)93069-8
Abstract
Reaction of phenyl benzoate with tri-n-butyltin hydride has been found to give mainly toluene, benzyl benzoate, tri-n-butyltin phenoxide and tri-n-butyltin benzoate. Possible reaction paths leading to these products are discussed. A SH2 mechanism involving initial attack of tri-n-butyltin radical at the ethereal oxygen atom of the ester with displacement of the benzoyl moiety appears to be consistent with observed experimental evidence. © 1970.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Hydrostannolysis; phenolic; esters; tri-n-butyltin hydride |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Mr Jasny Razali |
| Date Deposited: | 12 Mar 2021 01:31 |
| Last Modified: | 12 Mar 2021 01:31 |
| URI: | http://eprints.um.edu.my/id/eprint/24613 |
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