Goh, S.H. (1971) Nitrophenylcarbenes. Part I. The catalytic and photolytic decomposition of α-diazo-3-nitrotoluene in the presence of olefins. Journal of the Chemical Society C: Organic. pp. 2275-2278. ISSN 0022-4952, DOI https://doi.org/10.1039/J39710002275.
Full text not available from this repository.Abstract
The decomposition of α-diazo-3-nitrotoluene by zinc halides in the presence of olefins gave cyclopropane adducts in moderate yields. The addition of the carbenoid intermediate to unsymmetrically substituted olefins is syn-stereoselective. The free carbene species generated by photolysis also added readily to olefins. Non-stereospecific cyclopropane adducts and olefinic products were also formed, as a result of the involvement of both singlet and triplet 3-nitrophenylcarbenes.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Nitrophenylcarbenes; catalytic; photolytic; decomposition; α-diazo-3-nitrotoluene; olefins |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Mr Jasny Razali |
| Date Deposited: | 24 Mar 2021 05:28 |
| Last Modified: | 24 Mar 2021 05:28 |
| URI: | http://eprints.um.edu.my/id/eprint/24417 |
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