The induced decomposition of t-butyl peroxide in solution. Part III. Decomposition of t-butyl peroxide in alkyl benzyl ethers; steric effects

Goh, S.H. and Huang, R.L. and Ong, S.H. and Sieh, I. (1971) The induced decomposition of t-butyl peroxide in solution. Part III. Decomposition of t-butyl peroxide in alkyl benzyl ethers; steric effects. Journal of the Chemical Society C: Organic. pp. 2282-2286. ISSN 0022-4952

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Official URL: https://doi.org/10.1039/J39710002282

Abstract

Product and rate studies of the thermal decomposition of t-butyl peroxide in a series of alkyl benzyl ethers PhCH2·OR (R = Me, Et, Pri, But, or Ph) show little induced decomposition of the peroxide by the ether radical PhĊHOR, whereas in the case of the chloro-substituted ethers ArCH2·OR (Ar = 4-ClC 6H4 or 3,4-Cl2C6H3, R = Me, Et, Pri, But, or Ph) induced decomposition does occur to widely varying degrees, showing marked steric influence by the group R.

Item Type: Article
Uncontrolled Keywords: t-butyl peroxide; solution; decomposition; alkyl benzyl ethers; steric effects
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Mr Jasny Razali
Date Deposited: 24 Mar 2021 05:34
Last Modified: 24 Mar 2021 05:34
URI: http://eprints.um.edu.my/id/eprint/24416

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