Goh, S.H. and Huang, R.L. and Ong, S.H. and Sieh, I. (1971) The induced decomposition of t-butyl peroxide in solution. Part III. Decomposition of t-butyl peroxide in alkyl benzyl ethers; steric effects. Journal of the Chemical Society C: Organic. pp. 2282-2286. ISSN 0022-4952, DOI https://doi.org/10.1039/J39710002282.
Full text not available from this repository.Abstract
Product and rate studies of the thermal decomposition of t-butyl peroxide in a series of alkyl benzyl ethers PhCH2·OR (R = Me, Et, Pri, But, or Ph) show little induced decomposition of the peroxide by the ether radical PhĊHOR, whereas in the case of the chloro-substituted ethers ArCH2·OR (Ar = 4-ClC 6H4 or 3,4-Cl2C6H3, R = Me, Et, Pri, But, or Ph) induced decomposition does occur to widely varying degrees, showing marked steric influence by the group R.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | t-butyl peroxide; solution; decomposition; alkyl benzyl ethers; steric effects |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Mr Jasny Razali |
| Date Deposited: | 24 Mar 2021 05:34 |
| Last Modified: | 24 Mar 2021 05:34 |
| URI: | http://eprints.um.edu.my/id/eprint/24416 |
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