Ruthenium oxide/tungsten oxide composite nanofibers as anode catalysts for the green energy generation of Chlorella vulgaris mediated biophotovoltaic cells

Karthikeyan, Chandrasekaran and Raj Kumar, T. and Pannipara, Mehboobali and Al‐Sehemi, Abdullah G. and Senthilkumar, N. and Angelaalincy, M. J. and Varalakshmi, P. and Phang, Siew Moi and Periasamy, Vengadesh and Gnana kumar, G. (2019) Ruthenium oxide/tungsten oxide composite nanofibers as anode catalysts for the green energy generation of Chlorella vulgaris mediated biophotovoltaic cells. Environmental Progress & Sustainable Energy, 38 (6). e13262. ISSN 1944-7442, DOI https://doi.org/10.1002/ep.13262.

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Official URL: https://doi.org/10.1002/ep.13262

Abstract

The development of electrochemically active and stable anode catalysts for the photoelectrochemical splitting of water molecules via biophotovoltaic cells (BPVs) utilizing microalgae receives a prime importance in green energy sector. Herein, we report the ruthenium oxide (RuO2)/tungsten oxide (WO3) composite nanofibers based photoanode for the application of high performance and durable BPV. The sequential arrangement of 6 nm sized RuO2/WO3 spherical particles constitutes the nanofibrous morphology and a number of surface active sites and structural integrity of nanofibers demonstrate the excellent and stable photo-oxidation currents. Under the light regime, RuO2/WO3/carbon cloth photoanode exhibits the substantial BPV power and current densities with an excellent durability. Thus this systematic study evokes the fundamental understanding on the electron generation and transference mechanisms, which offers new dimensions in the development of high performance and durable BPVs. © 2019 American Institute of Chemical Engineers

Item Type: Article
Funders: Science and Engineering Research Board (SERB), New Delhi, India, Major Project Grant No.: EMR/ 2015/000912, Deanship of Scientific Research at King Khalid University for funding this work through the Research Group Project under grant number R. G. P.1/15/40, HICoE MOE:IOES-2014F Grant and Newton Prize 2017 (IF008-2018)
Uncontrolled Keywords: biophotovoltaic cell; green energy; microalgae; nanofiber; photocatalysis
Subjects: Q Science > QC Physics
Q Science > QD Chemistry
Q Science > QH Natural history
Divisions: Faculty of Science > Department of Physics
Faculty of Science > Institute of Biological Sciences
Deputy Vice Chancellor (Research & Innovation) Office > Institute of Ocean and Earth Sciences
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 13 Apr 2020 06:48
Last Modified: 13 Apr 2020 06:48
URI: http://eprints.um.edu.my/id/eprint/24201

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