Characterization of Sulfur-Compounds as Chemotaxonomic Markers in the Essential Oils of Allium Species by Solvent-Free Microwave Extraction and Gas Chromatography–Mass Spectrometry

Ikram, Rabia and Low, Kah Hin and Hashim, Najihah Mohd and Ahmad, Waqas and Nasharuddin, Muhammad Nazil Afiq (2019) Characterization of Sulfur-Compounds as Chemotaxonomic Markers in the Essential Oils of Allium Species by Solvent-Free Microwave Extraction and Gas Chromatography–Mass Spectrometry. Analytical Letters, 52 (4). pp. 563-574. ISSN 0003-2719, DOI https://doi.org/10.1080/00032719.2018.1479411.

Full text not available from this repository.
Official URL: https://doi.org/10.1080/00032719.2018.1479411

Abstract

Allium species were examined to authenticate the chemotaxonomic controversy about these plants by analyzing their extracted compound profiles. Essential oils of various species were isolated using conventional hydro-distillation and solvent-free microwave extraction (SFME). A comparison of the isolation procedures was performed. The presence of sulfur compounds in the Allium genus is a prominent characteristic for their medicinal uses. These components were characterized using two-way hierarchical cluster analysis (HCA) and principal component analysis (PCA). The variation of sulfur-compounds was performed by qualitative analysis of Allium species by gas chromatography–mass spectrometry (GC–MS). 2,4-Dimethyl-5,6-dithia-2,7-nonadienal, 4,6-diethyl-1,2,3,5-tetrathiolane, and 5,7-diethyl-1,2,3,4,6-pentathiepane were revealed as potential chemotaxonomic markers for all of the Alliums examined in this study. These markers may be used to provide improved systematics for other Allium species. © 2018, © 2018 Taylor & Francis.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: Essential oils; gas chromatography–mass spectrometry (GC–MS); hierarchical cluster analysis (HCA); principal component analysis (PCA); solvent-free microwave extraction (SFME)
Subjects: Q Science > QD Chemistry
R Medicine
Divisions: Faculty of Medicine
Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 22 Mar 2020 08:19
Last Modified: 22 Mar 2020 08:19
URI: http://eprints.um.edu.my/id/eprint/24074

Actions (login required)

View Item View Item