Removal of phthalates in aqueos samples using non-ionic silicone surfactant mediated cloud point extraction via spectrophotometry [Penyingkiran ftalat dalam sampel akues menggunakan teknik pengekstrakan titik awan surfaktan silikon tidak berionik dengan spektrofotometri]

Ooi, Pei Wan and Ramachandran, Muggundha Raoov and Yahaya, Noorfatimah and Nik Mohamed Kamal, Nik Nur Syazni and Gopal, Kasturi and Husin, Nor Aniisah and Zain, Nur Nadhirah Mohamad (2019) Removal of phthalates in aqueos samples using non-ionic silicone surfactant mediated cloud point extraction via spectrophotometry [Penyingkiran ftalat dalam sampel akues menggunakan teknik pengekstrakan titik awan surfaktan silikon tidak berionik dengan spektrofotometri]. Malaysian Journal of Analytical Sciences, 23 (5). pp. 839-848. ISSN 1394-2506,

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Official URL: http://www.ukm.my/mjas/v23_n5/html/23_5_9.html

Abstract

Removal of phthalates in environmental compartments become crucial in recent years due to the growing global concern about the health effects of phthalates. In this study, a greener method based on cloud point extraction procedure was developed for the removal of selected phthalates in environmental samples using non-ionic silicone surfactant (DC193C). The parameters affecting the extraction efficiency, such as the surfactant concentration, salt types, salt concentration, temperature and incubation time were evaluated and optimized. Good linearity with correlation coefficients (R2) in the range of 0.9963 – 0.9988 for all calibration curves was obtained. The proposed method was applied in removing the diethhylhexyl phthalate and dibutyl phthalate in river water samples under optimized conditions with satisfactory recoveries in the range of 82 – 98%. © 2019, Malaysian Society of Analytical Sciences. All rights reserved.

Item Type: Article
Funders: Universiti Sains Malaysia and the Ministry of Education Malaysia for financial support through the Bridging Grant (304.CIPPT.6316266) and Fundamental Research Grant Scheme (FRGS: 203.CIPPT.6711661)
Uncontrolled Keywords: cloud point extraction; non-ionic silicone surfactant; phthalates; spectrophotometry
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 14 Feb 2020 02:16
Last Modified: 14 Feb 2020 02:16
URI: http://eprints.um.edu.my/id/eprint/23787

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