Zhang, Kou-Lin and Lin, Jian-Guo and Ng, Seik Weng (2012) Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate]. Acta Crystallographica Section E: Structure Reports Online, 68 (3). m241-m241. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536812003613.
Full text not available from this repository.Abstract
The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C 8H 3O 7S)(C 12H 8N 2)(H 2O) 2]·2H 2O} n , bridges three water/phenanthroline-coordinated Dy III atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bonded to a monodentate carboxylate group and to a monodentate sulfonate group in a distorted square-anti-prismatic geometry. The coordinating and the solvent water molecules are hydrogen bonded to the network. In the crystal, one solvent water molecule is disordered over two positions [major component = 59 (3)%].
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | data-toparameter ratio = 11.4; disorder in solvent or counterion; mean σ(C-C) = 0.010 Å; R factor = 0.037; single-crystal X-ray study; T = 293 Kw; R factor = 0.093 |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 22 Nov 2019 07:18 |
| Last Modified: | 22 Nov 2019 07:18 |
| URI: | http://eprints.um.edu.my/id/eprint/23094 |
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