Development of an Alkaloid-Pyrone Annulation: Synthesis of Pleiomaltinine

Ziegler, Robert E. and Tan, Shin Jowl and Kam, Toh Seok and Porco, John A. (2012) Development of an Alkaloid-Pyrone Annulation: Synthesis of Pleiomaltinine. Angewandte Chemie International Edition, 51 (37). pp. 9348-9351. ISSN 1433-7851

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Official URL: https://doi.org/10.1002/anie.201204093

Abstract

Odd Couple: A method for the synthesis of alkaloid-pyrones using a novel pyrone annulation of β-carbolines and indoles with 3-siloxy-4-pyrones is reported. The approach has enabled synthesis of the unusual alkaloid-pyrone pleiomaltinine from the plant-derived indole-alkaloid pleiocarpamine (see Scheme; TBS= tert-butyldimethylsilyl). © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Item Type: Article
Uncontrolled Keywords: alkaloid; annulation; natural products; pyrones; quinone methides
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 22 Nov 2019 04:04
Last Modified: 22 Nov 2019 04:04
URI: http://eprints.um.edu.my/id/eprint/23086

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