Zeng, Cheng-Hui and Zhao, Fu-Li and Yang, Yang-Yi and Xie, Ming-Yuan and Ding, Xue-Mei and Hou, De-Jian and Ng, Seik Weng (2013) Unusual method for phenolic hydroxyl bridged lanthanide CPs: Syntheses, characterization, one and two photon luminescence. Dalton Transactions, 42 (6). pp. 2052-2061. ISSN 1477-9226, DOI https://doi.org/10.1039/c2dt32233a.
Full text not available from this repository.Abstract
A "basophilic method" for phenolic hydroxyl bridged lanthanide coordination polymers (CPs) was developed. With this method, eleven CPs with the general formula of [Ln(HL1)L1·H2O]n (Ln = Tb (1), Nd (2), Eu (3), Gd (4), La (5), Er (6), Y (7), H2L1 = 4-methyl salicylic acid) and [Ln(HL2)L2·2MeOH]n (Ln = Eu (8), Tb (9), Gd (10), La (11), H2L2 = 3-hydroxy-2-naphthoic acid) were synthesized based on two ligands, and five of them (1-4 and 8) were characterised by X-ray single crystal diffraction. The powder X-ray diffraction patterns (PXRD) of complexes showed that 1-7 are isostructural, 8-11 are isostructural. Furthermore, 1 was characterised by Fourier transform infrared (FT-IR), thermogravimetric analysis (TGA), differential thermal analysis (DTA), elemental analysis (EA), one and two photon luminescence were investigated in detail. © The Royal Society of Chemistry 2013.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | 3-Hydroxy-2-naphthoic acid; Fourier transform infrared; Isostructural; Lanthanide coordination polymer; Phenolic hydroxyl; Powder X ray diffraction; Salicylic acids; Two-photon luminescence; X-ray single-crystal diffraction |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry T Technology > TP Chemical technology |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 20 Nov 2019 04:32 |
| Last Modified: | 20 Nov 2019 04:32 |
| URI: | http://eprints.um.edu.my/id/eprint/23077 |
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