Zukerman-Schpector, Julio and Olivato, Paulo R. and Cerqueira Jr, Carlos R. and Contieri, Bruna and Ng, Seik Weng and Tiekink, Edward R.T. (2013) 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one. Acta Crystallographica Section E: Structure Reports Online, 69 (4). o556-o556. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536813006995.
Full text not available from this repository.Abstract
In the title compound, C18H17Br2NOS 2, the conformation of the piperidin-2-one ring is based on a half-chair with the methylene C atom diagonally opposite the N atom being 0.649 (3) Å above the plane of the remaining five atoms (r.m.s. deviation = 0.1205 Å). The S atoms occupy axial and bisectional positions, and the dihedral angle between the benzene rings of 59.95 (11)° indicates a splayed disposition. Helical supramolecular chains along the b axis sustained by C-H⋯O interactions is the major feature of the crystal packing. The chains are connected into a three-dimensional architecture by C-H⋯Br and C-H⋯π interactions.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Ketones; Infrared spectroscopy; Gas phase |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 19 Nov 2019 08:05 |
| Last Modified: | 19 Nov 2019 08:05 |
| URI: | http://eprints.um.edu.my/id/eprint/23063 |
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