On the role of DMSO-O(lone pair)⋯π(arene), DMSO-S(lone pair)⋯π(arene) and SO⋯π(arene) interactions in the crystal structures of dimethyl sulphoxide (DMSO) solvates

Zukerman-Schpector, Julio and Tiekink, Edward R.T. (2014) On the role of DMSO-O(lone pair)⋯π(arene), DMSO-S(lone pair)⋯π(arene) and SO⋯π(arene) interactions in the crystal structures of dimethyl sulphoxide (DMSO) solvates. CrystEngComm, 16 (28). pp. 6398-6407. ISSN 1466-8033, DOI https://doi.org/10.1039/C4CE00305E.

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Official URL: https://doi.org/10.1039/C4CE00305E

Abstract

Dimethyl sulphoxide (DMSO) molecules in their all-organic solvates were shown to interact with arene rings of organic molecules via DMSO-O(lone pair)⋯π(arene) or DMSO-S(lone pair)⋯π(arene) interactions in approximately 5-6% of their crystal structures, often in conjunction with conventional hydrogen bonding involving the O(DMSO) atom, resulting in zero-, one- and two-dimensional supramolecular architectures. Zero-, one- and two-dimensional supramolecular architectures were also found to be sustained by parallel SO⋯π(arene) interactions operating in combination with hydrogen bonding. © 2014 the Partner Organisations.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: Copper; Crystal structure; X-ray diffraction
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 19 Nov 2019 06:28
Last Modified: 19 Nov 2019 06:28
URI: http://eprints.um.edu.my/id/eprint/23056

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