Zhang, Jing and Li, Ping and Liu, Zhi-Hong and Ng, Seik Weng (2011) Hemipotassium hemirubidium digallium(III) manganese(II) tris(phosphate) dihydrate. Acta Crystallographica Section E: Structure Reports Online, 67 (5). i30-i30. ISSN 1600-5368, DOI https://doi.org/10.1107/S160053681101258X.
Full text not available from this repository.Abstract
The title manganese(II) substituted gallophosphate, K0.5Rb 0.5- [Ga2Mn(PO4)3(H 2O)2], features a three-dimensional network built of PO4 tetrahedra, GaO5 trigonal bipyramids and MnO 6 octahedra. The RbI and KI ions, which are disordered with respect to each other in a 1:1 ratio, occupy sites within the channels of the framework. The RbI/KI and MnII atoms occupy positions of 2 symmetry, as does one of the two P atoms. The RbI/KI site is surrounded by six O atoms [2.996 (2)-3.178 (4) Å] in an irregularly-shaped coordination environment. O-H⋯O hydrogen bonds between the water molecules and phosphate O atoms consolidate the crystal packing.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Crystal structure; Hydrogen bonds; Ref F |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 14 Nov 2019 07:28 |
| Last Modified: | 14 Nov 2019 07:28 |
| URI: | http://eprints.um.edu.my/id/eprint/23002 |
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