Zhang, Zhen-Hua and Wang, Hong-Mei and Niu, Yun-Yin and Wu, Ben-Lai and Ng, Seik Weng and Hou, Hong-Wei (2011) Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters. Inorganic Chemistry Communications, 14 (11). pp. 1783-1787. ISSN 1387-7003, DOI https://doi.org/10.1016/j.inoche.2011.08.009.
Full text not available from this repository.Abstract
Organic cation-templated self-assembly of 4,4′-bipy (4,4′-bipy = 4,4′-bipyridine) with [NH4]2MS2O 2 (M = Mo, W) and CuX (X = I) in the presence of bppt [bppt = 1, 5-bis (pyridinium) pentane] resulted in two novel neutral heterothiometallic cluster polymers: {[Mo2O2S6Cu 6BrI(4,4′-bipy)4] (4,4′-bipy)}n (1) and {[WOS3Cu3Br(4,4-bipy)2.5]•3 (DMF)}n (2). Compound 1 exhibits a neutral 3D 3-fold interpenetrating motif and compound 2 possesses a neutral 3D 4-fold interpenetrating architecture. Both of them have been characterized by IR, elemental analysis, TGA, UV-vis, PXRD, and single-crystal X-ray diffraction. The results may provide fascinating insights into the usage of template effect on the construction of the cluster-based coordination polymers. © 2011 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Funders: | National Natural Science Foundation (Grant No. 20671083) |
| Uncontrolled Keywords: | Cation-template; Mo(W)–S–Cu clusters; Bppt; Interpenetrating net |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 14 Nov 2019 04:01 |
| Last Modified: | 14 Nov 2019 04:01 |
| URI: | http://eprints.um.edu.my/id/eprint/22987 |
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