Hydrothermal preparation of reduced graphene oxide/tungsten trioxide nanocomposites with enhanced electrochemical performance

Wong, Christelle Pau Ping and Lee, Kian Mun and Lai, Chin Wei (2017) Hydrothermal preparation of reduced graphene oxide/tungsten trioxide nanocomposites with enhanced electrochemical performance. Journal of Materials Science: Materials in Electronics, 28 (19). pp. 14554-14567. ISSN 0957-4522, DOI https://doi.org/10.1007/s10854-017-7319-2.

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Official URL: https://doi.org/10.1007/s10854-017-7319-2

Abstract

A series of rGO/WO3 nanocomposites have been synthesized in this study using the single-step hydrothermal approach by varying the concentration of WO3 for supercapacitor applications. Accordingly, the effect of different WO3 contents on the electrochemical performance of rGO/WO3 was extensively studied. It was noteworthy that rGO/WO3 nanocomposite with mass ratio of 1:100 showed the highest specific capacitance (i.e., 274 F g−1 at current density of 0.7 A g−1) at 150 °C with a reaction time of 20 h. By careful control of the synthesis parameters, rGO/WO3 with fibers-like structure could be obtained. Correspondingly, this structure can lower the resistance and shorten the diffusion pathway coupled with offering more reactive sites for electrolyte. A possible growth mechanism of WO3 deposited on rGO was also proposed in the presence work. Additionally, this piece of work also provided a better understanding the roles of fiber-like WO3 anchored on rGO/WO3 nanocomposites for efficient electrochemical capacitor.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: Diffusion pathways; Electrochemical capacitor; Electrochemical performance; Hydrothermal preparation; Reduced graphene oxides; Specific capacitance; Supercapacitor application; Synthesis parameters
Subjects: Q Science > QC Physics
T Technology > TK Electrical engineering. Electronics Nuclear engineering
Divisions: Deputy Vice Chancellor (Research & Innovation) Office > Nanotechnology & Catalysis Research Centre
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 22 Oct 2019 03:55
Last Modified: 22 Oct 2019 03:55
URI: http://eprints.um.edu.my/id/eprint/22800

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