The synthesis of some novel stilbene dimers incorporating diamide tethers: studies in single electron transfer oxidation (FeCl3)

Alehashem, Maryam Sadat and Ariffin, Azhar and Al-Khdhairawi, Amjad Ayad Qatran and Thomas, Noel Francis (2018) The synthesis of some novel stilbene dimers incorporating diamide tethers: studies in single electron transfer oxidation (FeCl3). RSC Advances, 8 (5). pp. 2506-2520. ISSN 2046-2069, DOI https://doi.org/10.1039/c7ra12534h.

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Official URL: https://doi.org/10.1039/c7ra12534h

Abstract

The FeCl3 oxidative cascade reaction of the acetamido stilbene 1 which we reported some years ago produced the first atropodiastereomeric indolostilbene hybrid 3. By contrast, recent investigation of the oxidation of the stilbene succinamide dimer 72 (FeCl3/CH2Cl2) appears, on the basis of spectroscopic evidence, to have produced the bridged macrocyclic indoline 73.

Item Type: Article
Funders: University Malaya for the Postgraduate Research Grant (PPP)-Research PG178-2015A, Fundamental Research Grant Scheme (FRGS) FP044-2015A, Ministry of Higher Education (MOHE) Malaysia (HIR-005)
Uncontrolled Keywords: Acetamido; Cascade reactions; Diamides; Macrocyclics; Single electron transfer; Spectroscopic evidence; Succinamide
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 26 Sep 2019 03:10
Last Modified: 26 Sep 2019 03:10
URI: http://eprints.um.edu.my/id/eprint/22574

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