Shahriman, Mohamad Shariff and Zain, Nur Nadhirah Mohamad and Mohamad, Sharifah and Manan, Ninie Suhana Abdul and Yaman, Suhaila Mohd and Asman, Saliza and Raoov, Muggundha (2018) Polyaniline modified magnetic nanoparticles coated with dicationic ionic liquid for effective removal of rhodamine B (RB) from aqueous solution. RSC Advances, 8 (58). pp. 33180-33192. ISSN 2046-2069, DOI https://doi.org/10.1039/C8RA06687F.
Full text not available from this repository.Abstract
Polyaniline (PANI) modified magnetic nanoparticle (MNP) nanocomposites coated with newly synthesized dicationic ionic liquid (DICAT) forming MNP-PANI-DICAT were successfully synthesized as a potential material for the removal of Rhodamine B (RB) from water samples. The synthesized material was successfully characterized using a few techniques such as Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), thermo gravimetric analysis (TGA), Brunauer-Emmett-Teller (BET), and transmission electron microscopy (TEM) analysis. Several parameters have been optimized to enhance the efficiency of the removal process. The adsorption kinetics were investigated and the results showed that MNP-PANI-DICAT was best fitted to a pseudo-second order model for the adsorption of RB. As for the isotherm studies, Temkin's model was found to fit well with the adsorption isotherm of RB on MNP-PANI-DICAT. Other than that, thermodynamics results showed negative values of ΔG° for the adsorption of RB, which indicated that the process is thermodynamically feasible, spontaneous and chemically controlled at lower temperature. The negative value of enthalpy ΔH° (−40.41) indicated that the adsorption was an exothermic process. The percentage removal of RB was found to be 94.7% by MNP-PANI-DICAT under optimized conditions.
| Item Type: | Article |
|---|---|
| Funders: | Universiti Sains Malaysia of Research University Grant (RU:1001/CIPPT/811322), Fundamental Research Grant Scheme (FRGS:203/CIPPT/6711557), University of Malaya Research Grant (UM:RG381-17AFR) |
| Uncontrolled Keywords: | Brunauer emmett tellers; Dicationic ionic liquids; Fourier transform infra red (FTIR) spectroscopy; Magnetic nanoparticles; Optimized conditions; Potential materials; Pseudo-second order model; Synthesized materials |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 18 Mar 2019 04:18 |
| Last Modified: | 14 Feb 2020 02:06 |
| URI: | http://eprints.um.edu.my/id/eprint/20717 |
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