Identification of novel chemical structures of sulfo-imidazolium zwitterionic-type salt basis on 2D NMR analysis

Khaligh, Nader Ghaffari and Ling, Ong Chiu and Johan, Mohd Rafie and Juan, Joon Ching (2019) Identification of novel chemical structures of sulfo-imidazolium zwitterionic-type salt basis on 2D NMR analysis. Journal of Molecular Structure, 1180. pp. 280-284. ISSN 0022-2860, DOI https://doi.org/10.1016/j.molstruc.2018.11.106.

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Official URL: https://doi.org/10.1016/j.molstruc.2018.11.106

Abstract

The reaction of the equimolar mixture of imidazole and 1,4-butanesultone was performed at 90 °C in ethylbenzene for 12 h and the zwitterionic and ionic structures of the product investigated by the NMR analysis. The present work displayed the great importance of 2D NMR analysis on the structure elucidation of this sulfonic acid functionalized liquid salt. The results of NMR analysis demonstrate that 4-imidazole-1-yl-butane-1-sulfonic acid did not exist and really a mixture of zwitterionic and ionic compounds is produced.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: NMR analysis; Sulfo-functionalized liquid salt; Zwitterionic structure
Subjects: T Technology > TP Chemical technology
Divisions: Nanotechnology & Catalysis Research Centre
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 17 Jan 2019 09:13
Last Modified: 17 Jan 2019 09:13
URI: http://eprints.um.edu.my/id/eprint/20052

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