Wang, J. and Gu, C.Y. and Li, Q.L. and Lu, L. and Liu, J.Q. and Liu, W.C. and Yadav, R. and Kumar, A. and Ng, S.W. (2015) A combined experimental and theoretical investigation on solvent-dependent luminescence behavior of a Cu(I)-MOF. Inorganic Chemistry Communications, 61. pp. 82-84. ISSN 1387-7003, DOI https://doi.org/10.1016/j.inoche.2015.08.025.
Full text not available from this repository.Abstract
A new Cu(I)-based complex with chemical formulae [Cu7(CN)7(4,4′-bipy)] (1), (4,4′-bipy = 4,4′-bipyridine) has been synthesized and structurally characterized. Single-crystal X-ray analyses reveal that compound 1 exhibits threading network constructed by a 2D sheet and 1D chain. The photoluminescent property of 1 in different solvents has been investigated and corroborated by theoretical calculations. The obtained results are in good agreement with the results of solvent-dependent luminescence experimental behaviors. An extended analysis of experimental and computational result for 1 indicates that strong metal-solvent bonding interaction plays a dominant role in the sensing of various solvents.
| Item Type: | Article |
|---|---|
| Funders: | National Natural Science Foundation of China (21201044), Institute of Functionalized Materials (grant nos. 2011KY02 and 2012KY12 and 2014PY01), Innovation Training Project of Guangdong Medical University (2014ZYDM017, 2014ZYDM018 and 2014ZZDM001), College Students Innovation Training Project of Guangdong Province (201410571060), Opening Project of Key Laboratory of Green Catalysis of Sichuan Institutes of High Education (no. LYJ1207), Education Committee of Sichuan Province (no. 12ZA090, 14ZB0220 and 13ZB0131), Sichuan University of Science and Engineering (nos. 2014PY01, and 2015PY03), DST, New Delhi: project no. SB/FT/CS-018/2012 |
| Uncontrolled Keywords: | Threading network; Luminescence; Sensing effect |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 28 Sep 2018 08:26 |
| Last Modified: | 28 Sep 2018 08:26 |
| URI: | http://eprints.um.edu.my/id/eprint/19476 |
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