Yue, Z.L. and Feng, Y.Q. and Ng, S.W. (2015) A linear heterometallic bismuth-copper coordination polymer containing two types of organic ligands. Acta Crystallographica Section C: Structural Chemistry, 71 (2). pp. 100-102. ISSN 2053-2296, DOI https://doi.org/10.1107/S2053229614028125.
Full text not available from this repository.Abstract
In the linear coordination polymer catena-poly[[[aqua(1,10-phenanthroline-κ2 N,N')copper(II)]-μ-pyridine-2,6-dicarboxylato-κ4 O2:O2',N,O6-[(nitrato-κ2 O,O')bismuth(III)]-μ-pyridine-2,6-dicarboxylato-κ4 O2,N,O6:O6'] dihydrate], {[BiIIICuII(C7H3NO4)2(NO3)(C12H8N2)(H2O)]·2H2O} n , the BiIII cation is O,N,O'-chelated by the two pyridine-2,6-dicarboxylate ligands and O,O'-chelated by the nitrate anion, the nine coordinating atoms conferring a tricapped trigonal prismatic environment on the metal centre. Each pyridine-2,6-dicarboxylate ligand uses one of its carboxylate O atoms to bind to an aqua(1,10-phenanthroline)copper(II) unit, the Cu-O dative bonds giving rise to the formation of a ribbon motif. The CuII cation exhibits a square-pyramidal geometry. The ribbon motif propagates along the shortest axis of the triclinic unit cell and the solvent water molecules are hydrogen bonded to the same ribbon.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Crystal structure; Heterometallic coordination polymer; Bismuth-copper; Pyridine-2,6-dicarboxylic acid; One-dimensional coordination polymer |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 20 Sep 2018 06:28 |
| Last Modified: | 20 Sep 2018 06:28 |
| URI: | http://eprints.um.edu.my/id/eprint/19335 |
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