Zukerman-Schpector, J. and Olivato, P.R. and Traesel, H.J. and Valença, J. and Rodrigues, D.N.S. and Tiekink, E.R.T. (2015) Crystal structure of 2-methoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylethan-1-one. Acta Crystallographica Section E: Crystallographic Communications, 71 (1). o3-o4. ISSN 2056-9890, DOI https://doi.org/10.1107/S205698901402550X.
Full text not available from this repository.Abstract
In the title β-thiocarbonyl compound, C16H16O2S, the carbonyl and methoxy O atoms are approximately coplanar [O - C - C - O torsion angle = - 18.2 (5)°] and syn to each other, and the tolyl ring is orientated to lie over them. The dihedral angle between the planes of the two rings is 44.03 (16)°. In the crystal, supramolecular chains are formed along the c axis mediated by C - H⋯O interactions involving methine and methyl H atoms as donors, with the carbonyl O atom accepting both bonds; these pack with no specific intermolecular interactions between them.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Uncontrolled Keywords: | Crystal structure; [beta]-thiocarbonyl; C-H...O interactions |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 18 Sep 2018 08:30 |
| Last Modified: | 18 Sep 2018 08:30 |
| URI: | http://eprints.um.edu.my/id/eprint/19260 |
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