Amin, N.A.M. and Hussen, R.S.D. and Lee, S.M. and Halcovitch, N.R. and Jotani, M.M. and Tiekink, E.R.T. (2017) trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis. Acta Crystallographica Section E: Crystallographic Communications, 73 (5). pp. 667-672. ISSN 2056-9890, DOI https://doi.org/10.1107/S2056989017005072.
Full text not available from this repository.Abstract
The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octahedron. The crystal features C - H⋯F, C - H⋯Cl and C - H⋯π interactions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the molecular packing are clearly evident from the analysis of the Hirshfeld surface.
| Item Type: | Article |
|---|---|
| Funders: | Sunway University (award No. INT-RRO-2017-096), University of Malaya (award Nos. RP017A-2014AFR, PG239-2016\#65532;A), Ministry of Higher Education, Malaysia (MOHE) Fundamental Research Grant Scheme (award No. FP033-2014B) |
| Uncontrolled Keywords: | Crystal structure; Organotin; C—H...F interactions; Hirshfeld surface analysis |
| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 04 Sep 2018 05:34 |
| Last Modified: | 04 Sep 2018 05:34 |
| URI: | http://eprints.um.edu.my/id/eprint/19090 |
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