trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis

Amin, N.A.M. and Hussen, R.S.D. and Lee, S.M. and Halcovitch, N.R. and Jotani, M.M. and Tiekink, E.R.T. (2017) trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis. Acta Crystallographica Section E: Crystallographic Communications, 73 (5). pp. 667-672. ISSN 2056-9890

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Official URL: http://dx.doi.org/10.1107/S2056989017005072

Abstract

The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octahedron. The crystal features C - H⋯F, C - H⋯Cl and C - H⋯π interactions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the molecular packing are clearly evident from the analysis of the Hirshfeld surface.

Item Type: Article
Uncontrolled Keywords: Crystal structure; Organotin; C—H...F inter­actions; Hirshfeld surface analysis
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 04 Sep 2018 05:34
Last Modified: 04 Sep 2018 05:34
URI: http://eprints.um.edu.my/id/eprint/19090

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