Catena-poly[[diiodidocadmium] -μ- [4,4′-(2,3,5,6-tetramethyl-1,4- phenylene)bis-(methylene)]bis-(3,5-dimethyl-1H-pyrazole)-κ 2 N 2:N 2′]

Zhou, Yuan Yuan and Wang, Zhao Yang and Yang, Guan and Ng, Seik Weng (2011) Catena-poly[[diiodidocadmium] -μ- [4,4′-(2,3,5,6-tetramethyl-1,4- phenylene)bis-(methylene)]bis-(3,5-dimethyl-1H-pyrazole)-κ 2 N 2:N 2′]. Acta Crystallographica Section E: Structure Reports Online, 67 (8). m1037. ISSN 1600-5368

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Official URL: https://doi.org/10.1107/S1600536811025797

Abstract

The heterocylic ligand of the polymeric title compound, [CdI 2(C 22H 30N 4)], links two adjacent CdI 2 units, forming a chain running parallel to [ 01]. The Cd II atom is located on a twofold rotation axis and shows a distorted tetra-hedral CdI 2N 2 coordination. The mid-point of the benzene ring of the ligand lies on a center of inversion. There are no classical hydrogen-bonding interactions present.

Item Type: Article
Uncontrolled Keywords: data-to-parameter ratio = 21.5; mean σ(CC) = 0.008 Å; R factor = 0.054; single-crystal X-ray study; T = 293 K; wR factor = 0.134
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Mr. Faizal Hamzah
Date Deposited: 01 Aug 2011 03:59
Last Modified: 12 Nov 2019 04:44
URI: http://eprints.um.edu.my/id/eprint/1887

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