Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes

Zukerman-Schpector, J. and Yeo, C.I. and Tiekink, E.R.T. (2016) Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes. Zeitschrift fur Kristallographie Crystalline Materials, 231 (1). pp. 55-64. ISSN 2194-4946, DOI https://doi.org/10.1515/zkri-2015-1868.

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Official URL: https://doi.org/10.1515/zkri-2015-1868

Abstract

A review of the crystallographic literature is presented whereby structures featuring a quasi-six-membered chelate ring of the type {CuCl⋯HNCS} were evaluated for the presence of intermolecular C-H⋯π(quasi-chelate) interactions. These are shown to stabilise crystal structures leading to zero-, one-, two- and even three-dimensional architectures. Details of these interactions are described and a comparison to analogous interactions formed intramolecularly has been made. The C-H⋯π(quasi-chelate) interactions in these structures occur in one-third of structures where such contacts can potentially form.

Item Type: Article
Funders: UNSPECIFIED
Uncontrolled Keywords: C–H…π interactions; Quasi-chelate rings; Supramolecular chemistry; Weak interactions; π-interactions
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 14 May 2018 06:15
Last Modified: 20 May 2020 00:28
URI: http://eprints.um.edu.my/id/eprint/18651

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