Magnetic solid phase extraction of polycyclic aromatic hydrocarbons and chlorophenols based on cyano-ionic liquid functionalized magnetic nanoparticles and their determination by HPLC-DAD

Bakhshaei, S. and Kamboh, M.A. and Nodeh, H.R. and Zain, S.M. and Mahmad Rozi, S.K. and Mohamad, S. (2016) Magnetic solid phase extraction of polycyclic aromatic hydrocarbons and chlorophenols based on cyano-ionic liquid functionalized magnetic nanoparticles and their determination by HPLC-DAD. RSC Advances, 6 (80). pp. 77047-77058. ISSN 2046-2069

Full text not available from this repository.
Official URL: https://doi.org/10.1039/c6ra13702d

Abstract

A magnetic solid-phase extraction (MSPE) procedure on the newly synthesized cyano-ionic liquid functionalized magnetic nanoparticles (MNP@CN/IL) was established and validated for the separation/preconcentration of polycyclic aromatic hydrocarbons (PAHs) and chlorophenols (CPs) from water samples prior to their HPLC-DAD determination. The new magnetic (MNP@CN/IL) adsorbent was characterized by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), elemental analysis (CHNS), energy-dispersive X-ray spectroscopy (EDX), vibrating sample magnetometry (VSM), thermal gravimetric analysis (TGA) and transmission electron microscopy (TEM). The proposed method showed preconcentrations of 200 and 100 with low limits of detection (LOD = 0.40-0.59 and 0.35-0.67 μg L-1) with linearity ranges from 0.1-100 and 3-100 μg L-1 for PAHs and CPs, respectively. The extraction recoveries from environmental samples (leachate and sludge from a landfill site) ranged from 89.50-110.2% and 80.67-112.7% for PAHs and CPs, respectively, with satisfactory precision (% RSD less than 5%). The combination of cyano group and ionic liquid on the surface of the MNPs enhanced the extraction efficiency which might be due to π-π interactions as well as electrostatic interactions.

Item Type: Article
Uncontrolled Keywords: Aromatic compounds; Aromatic hydrocarbons; Effluent treatment; Energy dispersive spectroscopy
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Dept of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 05 Dec 2017 03:49
Last Modified: 05 Dec 2017 03:49
URI: http://eprints.um.edu.my/id/eprint/18448

Actions (login required)

View Item View Item