Effect of nitrogen flow rate on structural, morphological and optical properties of In-rich InxAl1-xN thin films grown by plasma-assisted dual source reactive evaporation

Alizadeh, M. and Ganesh, V. and Goh, B.T. and Dee, C.F. and Mohmad, A.R. and Rahman, S.A. (2016) Effect of nitrogen flow rate on structural, morphological and optical properties of In-rich InxAl1-xN thin films grown by plasma-assisted dual source reactive evaporation. Applied Surface Science, 378. pp. 150-156. ISSN 0169-4332, DOI https://doi.org/10.1016/j.apsusc.2016.03.174.

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Official URL: https://doi.org/10.1016/j.apsusc.2016.03.174

Abstract

In-rich InxAl1-xN thin films were deposited on quartz substrate at various nitrogen flow rates by plasma-assisted dual source reactive evaporation technique. The elemental composition, surface morphology, structural and optical properties of the films were investigated by X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), Raman spectroscopy, X-ray diffraction (XRD), UV-vis spectrophotometer and photoluminescence (PL) measurements. XPS results revealed that the indium composition (x) of the InxAl1-xN films increases from 0.90 to 0.97 as the nitrogen flow rate is increased from 40 to 100 sccm, respectively. FESEM images of the surface and cross-sectional microstructure of the InxAl1-xN films showed that by increasing the N2 flow rate, the grown particles are highly agglomerated. Raman and XRD results indicated that by increasing nitrogen flow rate the In-rich InxAl1-xN films tend to turn into amorphous state. It was found that band gap energy of the films are in the range of 0.90-1.17 eV which is desirable for the application of full spectra solar cells.

Item Type: Article
Funders: University of Malaya, High Impact Research (HIR) fund of UM.C/HIR/MOHE/SC/06, Ministry of Higher Education Fundamental Research Grant Scheme (FRGS) of FP009-2013B, University of Malaya postgraduate research Fund (PPP) of PG081-2012B
Uncontrolled Keywords: InxAl1−xN; Plasma-assisted deposition; Raman spectra; Band gap
Subjects: Q Science > Q Science (General)
Q Science > QC Physics
Divisions: Faculty of Science > Department of Physics
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 13 Nov 2017 06:08
Last Modified: 13 Nov 2017 06:08
URI: http://eprints.um.edu.my/id/eprint/18241

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