Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

Ibrahim, S. and Woi, P.M. and Alias, Y. and Pickett, C.J. (2010) Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix. Chemical Communications, 46 (43). pp. 8189-8191.

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Abstract

We show that a redox active {Fe(4)S(4)}(2+)-cubane assembly covalently bound within a cysteinyl-alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

Item Type: Article
Subjects: R Medicine
Depositing User: MR Faizal II H
Date Deposited: 28 Dec 2015 08:29
Last Modified: 03 Jul 2017 08:57
URI: http://eprints.um.edu.my/id/eprint/15354

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