Johnson, S. and Musie, G.T. and Tiekink, E.R.T. (2010) 1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate. Acta Crystallographica Section E: Structure Reports Online, 66 (1). O64-U1625. ISSN 1600-5368,
Full text not available from this repository.Abstract
In the title salt hydrate, C(22)H(30)N(2)O(6)(2+)center dot 2Cl(-)center dot CH(4)O, the dication adopts a U-shaped conformation whereby the benzene rings are splayed out from the chain linking them. All components of the asymmetric unit are linked into a cohesive entity by a combination of O-H center dot center dot center dot Cl(-), N(+)-H center dot center dot center dot Cl(-) and N(+)-H center dot center dot center dot O charge-assisted hydrogen-bonding interactions. The assemblies thus formed are linked into supramolecular helical chains along [010] via C-H center dot center dot center dot O contacts. The resulting chains are, in turn, consolidated into the three-dimensional crystal structure by C-H center dot center dot center dot pi contacts.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > QC Physics |
| Depositing User: | Dr Mohd Faizal Hamzah |
| Date Deposited: | 28 Dec 2015 01:10 |
| Last Modified: | 31 Jan 2019 04:27 |
| URI: | http://eprints.um.edu.my/id/eprint/15297 |
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