Bis(mu-4-hydroxybenzoato-kappa O-2:O `)bis[triaquabis(4-hydroxybenzoato)-kappa O;kappa O-2,O `-terbium(III)] decahydrate

Zhu, Y.M. and Feng, P.P. and Yang, Y.Y. and Ng, S.W. (2010) Bis(mu-4-hydroxybenzoato-kappa O-2:O `)bis[triaquabis(4-hydroxybenzoato)-kappa O;kappa O-2,O `-terbium(III)] decahydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (1). M54-U617. ISSN 1600-5368,

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Abstract

The title dinuclear compound, [Tb-2(C7H5O3)(6)(H2O)(6)]center dot 10H(2)O, lies on a center of inversion and the two Tb-III atoms are bridged by two 4-hydroxybenzoate anions; each metal atom is further coordinated by one monodentate anion and chelated by the third anion. The eight-coordinate geometry approximates a square antiprism. Hydrogen bonds of the O-H center dot center dot center dot O type connect the uncoordinated water molecules to the dinuclear species, forming a three-dimensional network.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Dr Mohd Faizal Hamzah
Date Deposited: 23 Dec 2015 02:55
Last Modified: 30 Jan 2019 08:15
URI: http://eprints.um.edu.my/id/eprint/15282

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