catena-Poly[[[dichloridozinc(II)]-mu-1,4-bis(1H-benzimidazol-2-yl- kappa N-3)butane]1,4-bis(1H-benzimidazol-2-yl)butane solvate]

Zhou, Y.L. and Zeng, M.H. and Ng, S.W. (2010) catena-Poly[[[dichloridozinc(II)]-mu-1,4-bis(1H-benzimidazol-2-yl- kappa N-3)butane]1,4-bis(1H-benzimidazol-2-yl)butane solvate]. Acta Crystallographica Section E: Structure Reports Online, 66 (1). M58-U653. ISSN 1600-5368

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In the crystal structure of the title coordination polymer/co-crystal, {[ZnCl2(C18H18N4)]center dot C18H18N4}(n), the tetrahedrally coordinated Zn-II ions are linked by the N-heterocycle into a linear chain. Another N-heterocycle present is not coordinated to the metal atom but interacts with the chain through N-H center dot center dot center dot N and N-H center dot center dot center dot Cl hydrogen bonds. The butyl chain of the uncoordinated ligand is disordered over three positions in a 0.511 (4):0.289 (5):0.200 (5) ratio.

Item Type: Article
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 23 Dec 2015 03:06
Last Modified: 30 Jan 2019 08:15

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