Ling, I. and Alias, Y. and Sobolev, A.N. and Raston, C.L. (2010) p-Sulfonatocalix[4]arene-pyrrolidinium complexation in building multicomponent layered arrays. Crystal Growth & Design, 10 (3). pp. 1312-1318.
Full text not available from this repository.Abstract
p-Sulforiatocalix[4]arene and monophosphonium ions, in the presence of N-butyl-N-methylpyrrolidinium ions and aquated lanthanide ions, assemble into bilayers comprised of calixarenes with the phosphonium cations embedded between them; pyrrolidinium ions reside in the calixarene cavities which are normal to the bilayer plane. Replacing the phosphonium cations with bis-phosphonium ions results in the same interplay of the calixarene and pyrrolidinium cations, but with the formation of a different layered structure, which is now devoid of lanthanide ions, unlike the other bilayers, with all the sulfonate groups of the calixarenes residing in a plane with adjacent calixarenes in alternating directions. In aqueous solutions, it 1:1 supermolecule of the calixarene and pyrrolidinium ion is evident in aqueous solution using (1)H NMR spectroscopy.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > QD Chemistry |
| Depositing User: | Dr Mohd Faizal Hamzah |
| Date Deposited: | 21 Dec 2015 07:57 |
| Last Modified: | 21 Dec 2015 07:57 |
| URI: | http://eprints.um.edu.my/id/eprint/15124 |
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