Bis(phenylsulfinyl)methane

Wardell, S.M.S.V. and de Lima, G.M. and Wardell, J.L. and Tiekink, E.R.T. (2010) Bis(phenylsulfinyl)methane. Acta Crystallographica Section E: Structure Reports Online, 66 (3). O653-U5344. ISSN 1600-5368,

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Abstract

Two independent molecules comprise the asymmetric unit of the title compound, C13H12O2S2, which differ in terms of minor variations in the relative orientations of the benzene rings [the O-S-C-C torsion angles for the first independent molecule are -6.66 (17) and -12.88 (19)degrees compared with -21.70 (18) and 4.83 (16)degrees for the second molecule]. Supra-molecular chains sustained by C-H center dot center dot center dot O contacts and aligned along the a axis are found in the crystal structure. These are held in place in the three dimensional structure by C-H center dot center dot center dot pi interactions.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Dr Mohd Faizal Hamzah
Date Deposited: 02 Dec 2015 03:28
Last Modified: 30 Jan 2019 08:25
URI: http://eprints.um.edu.my/id/eprint/15034

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