Wardell, J.L. and Wardell, S.M.S.V. and Tiekink, E.R.T. and de Lima, G.M. (2010) Bis(2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperi din-1-ium) tetrachloridodiphenylstannate(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (3). M336-U3878. ISSN 1600-5368,
Full text not available from this repository.Abstract
In the title salt, (C17H17F6N2O)(2)[Sn(C6H5)(2)Cl-4], the complete anion is generated by crystallograaphic inversion symmetry, giving a trans-SnC2Cl4 octahedral coordination geometry for the metal atom. In the cation, the quinoline residue is almost normal to the other atoms, so that the ion has an L-shaped conformation [the C-C-C-C torsion angle linking the fused-ring systems is 100.9 (7)degrees]; the six-membered piperidin-1-ium ring has a chair conformation. An intramolecular N-H center dot center dot center dot O interaction occurs. In the crystal, N-H center dot center dot center dot Cl and O-H center dot center dot center dot Cl hydrogen bonds link the components into a supra-molecular chain propagating along the a axis. C-H center dot center dot center dot Cl interactions are also present.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Dr Mohd Faizal Hamzah |
| Date Deposited: | 02 Dec 2015 03:32 |
| Last Modified: | 30 Jan 2019 08:23 |
| URI: | http://eprints.um.edu.my/id/eprint/15013 |
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