Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate]

Sadeghi, O. and Amini, M.M. and Ng, S.W. (2010) Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate]. Acta Crystallographica Section E: Structure Reports Online, 66 (3). M285-U3404. ISSN 1600-5368,

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Abstract

In the crystal structure of {[Ag(C6H4NO2)(C18H15P)]center dot C2H6O}(n), the 4-pyridylcarboxylate ion binds to the phosphine-coordinated silver atoms through one of the two oxygen atoms of the carboxyl unit, and to a third phosphine-coordinate silver atom through the nitrogen atom of the aromatic ring, giving a distorted tetrahedral coordination at the metal atom. The mu(3)-bridging mode leads to a layer motif; the disordered ethanol molecules are linked to the free carboxyl oxygen atom by O-H center dot center dot center dot O hydrogen bonds.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 02 Dec 2015 03:03
Last Modified: 31 Jan 2019 04:51
URI: http://eprints.um.edu.my/id/eprint/15012

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