4-Methylbenzohydrazidato-kappa N-2 `,O)[2-(4-methylbenzoylhydrazinylidene-kappa N-2,O)-3-phenylpropionato(2-)]oxidovanadium(V) methanol monosolvate

Wong, H.W. and Lo, K.M. and Ng, S.W. (2010) 4-Methylbenzohydrazidato-kappa N-2 `,O)[2-(4-methylbenzoylhydrazinylidene-kappa N-2,O)-3-phenylpropionato(2-)]oxidovanadium(V) methanol monosolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (4). M481-U1339. ISSN 1600-5368,

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Abstract

The V V atom in the title compound, [V(C8H9N2O)(C17H14N2O3) O]center dot CH3OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O'-chelated by the (benzoylhydrazono)propionate dianion. The octahedral trans-N2O4 coordination geometry is completed by the vanadyl O atom. Two mononuclear complexes and two solvent molecules are linked by O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds, generating a centrosymmetric aggregate.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 13 Nov 2015 08:15
Last Modified: 30 Jan 2019 08:26
URI: http://eprints.um.edu.my/id/eprint/14782

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