Bis(mu-diphenylarsine-kappa As-2:As)bis[tetracarbonyltungsten(0)]

Tiekink, E.R.T. and Wardell, J.L. (2010) Bis(mu-diphenylarsine-kappa As-2:As)bis[tetracarbonyltungsten(0)]. Acta Crystallographica Section E: Structure Reports Online, 66 (4). M364-U300. ISSN 1600-5368,

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Abstract

The title compound, [W-2(C12H10As)(2)(CO)(8)], features a diamond-shaped W2As2 core with a W-W distance of 3.0948 (7) angstrom. The coordination geometry for each W atom is based on a pentagonal bipyramid within a As2C4W donor set, with carbonyl ligands defining the axial positions; the As atoms exist within distorted tetrahedral C2W2 donor sets.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 13 Nov 2015 08:11
Last Modified: 30 Jan 2019 08:42
URI: http://eprints.um.edu.my/id/eprint/14779

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