[(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)

Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I). Acta Crystallographica Section E: Structure Reports Online, 66 (4). M421-U800. ISSN 1600-5368,

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Abstract

The Au atom in the title compound, [Au(C(11)H(14)NOS)-(C(18)H(33)P)], is coordinated within an S, P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.060 (3) angstrom]. In the crystal structure, molecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H center dot center dot center dot pi.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 24 Nov 2015 01:15
Last Modified: 30 Jan 2019 09:02
URI: http://eprints.um.edu.my/id/eprint/14777

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