[(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)

Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I). Acta Crystallographica Section E: Structure Reports Online, 66 (4). M450-U1045. ISSN 1600-5368,

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Abstract

Two independent molecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclohexyl groups as well as the benzene ring. In each molecule, the Au atom is coordinated within a S, P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10 (5) and 177.26 (5)degrees for the two molecules], with the distortion due in part to the close intramolecular approach of the O atom [Au center dot center dot center dot O contacts = 3.054 (4) and 3.013 (4) angstrom, respectively, for the two molecules].

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 24 Nov 2015 01:18
Last Modified: 30 Jan 2019 09:03
URI: http://eprints.um.edu.my/id/eprint/14775

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