Bis[mu-4-hydroxy-N `-(4-methoxy-2-oxidobenzylidene)benzohydrazidato]bis[pyridinecopper(II )]

Lair, N.M. and Khaledi, H. and Ali, H.M. and Puteh, R. (2010) Bis[mu-4-hydroxy-N `-(4-methoxy-2-oxidobenzylidene)benzohydrazidato]bis[pyridinecopper(II )]. Acta Crystallographica Section E: Structure Reports Online, 66 (4). M470-U1240. ISSN 1600-5368

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Abstract

In the title compound, [Cu(2)(C(15)H(12)N(2)O(4))(2)(C(6)H(5)N)(2)], each Cu(II) atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine molecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 angstrom). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu-O interactions and also O-H center dot center dot center dot N hydrogen bonds.

Item Type: Article
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 20 Nov 2015 08:54
Last Modified: 29 Jan 2019 09:12
URI: http://eprints.um.edu.my/id/eprint/14767

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