Combined effect of CuO nanofillers and DBP plasticizer on ionic conductivity enhancement in the solid polymer electrolyte PEO-LiCF3SO3

Johan, M.R. and Fen, L.B. (2010) Combined effect of CuO nanofillers and DBP plasticizer on ionic conductivity enhancement in the solid polymer electrolyte PEO-LiCF3SO3. Ionics, 16 (4). pp. 335-338. ISSN 0947-7047,

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Abstract

We report a new kind of polyethylene oxide, PEO-LiCF3SO3-based composite polymer electrolyte, containing active copper oxide (CuO) nanoparticles with dibutyl phthalate (DBP) prepared by solution-cast technique. The incorporation of 10 wt.% DBP and 5 wt.% CuO to the salted polymer showed a significant conductivity enhancement with maximum conductivity 2.62 x 10(-4) Scm(-1) at room temperature. This could be attributed to the increasing of amorphous phase content and structural changes in the polymer electrolyte. Arrhenius plot suggest that temperature-dependent conductivity is a thermally activated process.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Dr Mohd Faizal Hamzah
Date Deposited: 11 Nov 2015 01:54
Last Modified: 04 Mar 2019 02:28
URI: http://eprints.um.edu.my/id/eprint/14719

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