Ou, Guang-Chuan and Ng, S.W. (2011) Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate. Acta Crystallographica Section E: Structure Reports Online, 67 (12). O1664-U1342. ISSN 1600-5368,
Full text not available from this repository.Abstract
In the title salt, [NaZn2(CH3COO)(2)(ClO4)(2)(C16H36N4)(2)]ClO4, the macrocyclic ligand binds to the Zn2+ cations through their four amino N atoms; the Zn2+ cations are also each covalently bonded to an acetate ion. For one zinc atom, the acetate group is monodentate, and the geometry is a distorted ZnN4O trigonal bipyramid; for the other, the acetate group is anisobidentate and the geometry is a distorted ZnN4O2 octahedron. The two macrocycle-zinc acetate units are bridged through a diperchloratosodium unit. In the crystal, the complex cations and uncoordinated perchlorate anions are linked by N-H center dot center dot center dot O hydrogen bonds.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > QC Physics |
| Depositing User: | Dr Mohd Faizal Hamzah |
| Date Deposited: | 07 Nov 2015 07:39 |
| Last Modified: | 31 Jan 2019 05:11 |
| URI: | http://eprints.um.edu.my/id/eprint/14664 |
Actions (login required)
 |
View Item |
