Roy, T.G. and Hazari, S.K.S. and Barua, K.K. and Ng, S.W. and Tiekink, E.R.T. (2011) Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetra azacyclotetradeca-4,11-diene]cobalt(III) perchlorate. Acta Crystallographica Section E: Structure Reports Online, 67 (12). M1722-U259. ISSN 1600-5368,
Full text not available from this repository.Abstract
The Co(III) atom in the title complex, [CoCl(2)(C(40)H(48)N(4))]ClO(4), is octahedrally coordinated within a trans-Cl(2)N(4) donor set provided by the tetradentate macrocylic ligand and two chloride ions. The N-H atoms, which are orientated to one side of the N(4) plane, form hydrogen bonds with chloride ions and perchlorate-O atoms. These along with C-H center dot center dot center dot O interactions consolidate the three-dimensional crystal structure. One of the benzene rings was disordered. This was resolved over two positions with the major component of the disorder having a site-occupancy factor of 0.672 (4).
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > QC Physics |
| Depositing User: | MR Faizal II H |
| Date Deposited: | 07 Nov 2015 06:47 |
| Last Modified: | 16 Apr 2019 11:38 |
| URI: | http://eprints.um.edu.my/id/eprint/14652 |
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