Wu, Xiang-Xiang and Zhu, Xin and Ma, Qiu-Juan and Ng, S.W. and Tiekink, E.R.T. (2011) (2-Bromoacetyl)ferrocene. Acta Crystallographica Section E: Structure Reports Online, 67 (12). M1875-U649. ISSN 1600-5368,
Full text not available from this repository.Abstract
In the title molecule, [Fe(C5H5)(C7H6BrO)], the C atoms of the substituted ring have disparate Fe-C bond lengths compared with the unsubstituted ring. In the bromoacetyl residue, the Br and O atoms are co-planar [the O-C-C-Br torsion angle is 5.7 (4)degrees] and are syn to each other. Helical supramolecular chains along the b axis are formed in the crystal structure mediated by C-H center dot center dot center dot O contacts; the carbonyl-O atom is bifurcated. The chains are linked into layers by C-H center dot center dot center dot pi (unsubstituted ring) interactions that stack along the a-axis direction.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > QC Physics |
| Depositing User: | Dr Mohd Faizal Hamzah |
| Date Deposited: | 07 Nov 2015 02:27 |
| Last Modified: | 30 Jan 2019 08:28 |
| URI: | http://eprints.um.edu.my/id/eprint/14628 |
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