Daud, M.N. (2011) UV photolysis of N2O isotopomers: Isotopic fractionations and product rotational quantum state Distributions. Chinese Journal of Chemical Physics, 24 (6). pp. 679-685.
Full text not available from this repository.Abstract
The time-dependent quantum wave packet method is used to study the dynamics of the photodissociation processes for the isotopomers (NNO)-N-14-N-14-O-16, (NNO)-N-14-N-15-O-16, (NNO)-N-15-N-14-O-16, (NNO)-N-15-N-15-O-16, (NNO)-N-14-N-14-O-17 and (NNO)-N-14-N-14-O-18. In general, the computed isotopic fractionation factors derived from the absorption cross sections of five heavy isotopomers are in good agreement with the experimental results. Relative to the (NNO)-N-14-N-14-O-16 isotopomer, the N-2 rotational state distributions for the isotopically nitrogen substituted N2O are found to be entirely shifted to higher rotational states. Similar to its isotopic fractionation factors, the N-2 rotational state distributions for the asymmetric isotopomers (NNO)-N-14-N-15-O-16, (NNO)-N-15-N-14-O-16 are found to be observably different.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Dr Mohd Faizal Hamzah |
| Date Deposited: | 07 Nov 2015 02:08 |
| Last Modified: | 07 Nov 2015 02:08 |
| URI: | http://eprints.um.edu.my/id/eprint/14619 |
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