Tiekink, E.R.T. and Wardell, J.L. and Fernandes, C. and Horn, A. and Skakle, J.M.S. (2010) mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amin o]methyl}phenolato)dinickel(II) chloride. Acta Crystallographica Section E: Structure Reports Online, 66 (5). M566-U904. ISSN 1600-5368,
Full text not available from this repository.Abstract
The title salt, [Ni(2)(C(16)H(18)ClN(2)O(2))(2)(CH(3)COO)]Cl, features a dinuclear cation in which the Ni atoms are triply bridged by two phenolate O ligands and a bidentate acetate ligand with all of the bridging distances essentially symmetric. Each Ni atom is also coordinated by the amine N, pyridine N and hydroxy O atoms of the 2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl) amino]methyl} phenolate ligand which is, therefore, pentadentate. The resultant N(3)O(3) donor sets define octahedral coordination geometries. The chloride counter-anion is connected to the cation via two Ohydroxy-H center dot center dot center dot Cl hydrogen bonds.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > QC Physics |
| Depositing User: | MR Faizal II H |
| Date Deposited: | 02 Nov 2015 07:11 |
| Last Modified: | 30 Jan 2019 08:43 |
| URI: | http://eprints.um.edu.my/id/eprint/14446 |
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