[O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)

Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I). Acta Crystallographica Section E: Structure Reports Online, 66 (5). M498-U309. ISSN 1600-5368,

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Abstract

The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S, P-donor set [S-Au-P = 177.62 (5)degrees]. The distortion is ascribed to the close approach of the O atom, which forms an intramolecular contact of 2.970 (5) angstrom. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the ethoxy group.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > Q Science (General)
Depositing User: Dr Mohd Faizal Hamzah
Date Deposited: 23 Oct 2015 02:26
Last Modified: 30 Jan 2019 09:00
URI: http://eprints.um.edu.my/id/eprint/14277

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