5-Methyl-2,4-bis(methylsulfanyl)tricyclo[6.2.1.0(2,7)]undeca-4,9-diene -3,6-dione

von Richthofen, A.A. and Cardoso Filho, J.E.P. and Marzorati, L. and Zukerman-Schpector, J. and Tiekink, E.R.T. and Di Vitta, C. (2010) 5-Methyl-2,4-bis(methylsulfanyl)tricyclo[6.2.1.0(2,7)]undeca-4,9-diene -3,6-dione. Acta Crystallographica Section E: Structure Reports Online, 66 (6). O1259-U131. ISSN 1600-5368,

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Abstract

The structure analysis of the title compound, C14H16O2S2, shows the SMe and H atoms of the bond linking the six-membered rings to be syn and also to be syn to the bridgehead -CH2- group. Each of the five-membered rings adopts an envelope conformation at the bridgehead -CH2- group. The dione-substituted ring adopts a folded conformation about the 1,4-C center dot center dot center dot C vector, with the ketone groups lying to one side. The cyclohexene ring adopts a boat conformation.

Item Type: Article
Funders: UNSPECIFIED
Subjects: Q Science > QD Chemistry
Depositing User: Mr Faizal 2
Date Deposited: 20 Apr 2015 02:40
Last Modified: 30 Jan 2019 08:33
URI: http://eprints.um.edu.my/id/eprint/13294

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